在文献中看到“γ effect ”这个概念,不知道是什么意思,有没有哪位高人指点下?
. H) _6 \5 M5 p/ v* b原文是这样说的: a 'tentative assignment is proposed.% L. {* p( @6 ?+ K9 x1 O
Such an assignment is based on consideration of the, h0 Q8 V5 m" X& H7 a
“γ effect,” i.e. the steric polarization shift which* F3 J7 L$ ~$ k) }$ ~
has been observed whenever a carbon is close to a
1 S2 j4 W4 [" n& c. W* Oγ-carbon or a γ-oxygen.' m3 c3 |8 h2 y* h# c4 j! R
不明白这句话的意思,steric polarization shift 指的是什么啊,望不吝赐教,谢谢! |